The 44th edition of WWE Superstars came to you from the Wells Fargo Arena in Des Moines, IA and from the Sprint Center in Kansas City, MO. Three nights before he steps into the Elimination Chamber to battle for the World Heavyweight Championship, Rey Mysterio would go one-on-one with Mike Knox. Brothers and former tag team champions would be on opposing teams as Carlito would team with Chavo Guerrero to face his brother Primo and his tag partner, Evan Bourne. Three nights before she faces Maryse in the Finals of the Divas Tournament to determine the Divas Champion at the Elimination Chamber event, Gail Kim would go one-on-one with Katie Lea.
- Primo & Evan Bourne def. Carlito & Chavo Guerrero by Evan Bourne pinning Chavo Guerrero following Air Bourne.
- Gail Kim def. Katie Lea by pin following the Eat Defeat.
- Rey Mysterio def. Mike Knox by pin with the 619NS.
- Primo & Evan Bourne Vs. Carlito & Chavo Guerrero
- Gail Kim Vs. Katie Lea
- Rey Mysterio Vs. Mike Knox
The show kicks off with the opening match of the night as brothers and former Unified WWE Tag Team Champions face off on opposing teams as Carlito would team up with Chavo Guerrero to face his brother, Primo, and his partner, Evan Bourne. In the end, it was the high-flying team of Primo & Evan Bourne picking up the win as Evan Bourne hit Air Bourne en route to pinning Chavo Guerrero for the win in a hard-fought match!
The Divas were in action on WWE Superstars as one of the two Finalists in the Divas Tournament, Gail Kim, went one-on-one with Katie Lea. Despite an injured shoulder, Gail Kim was able to hit the Eat Defeat on Katie Lea to pick up the win, and the momentum, heading into her match with Maryse this Sunday at WWE Elimination Chamber to determine who will win the currently vacant Divas Title. Can Gail Kim carry her momentum to St. Louis this Sunday and defeat Maryse to win the Divas Title or will Maryse emerge victorious as the first two-time champion in the history of the Divas Title?
Then it was time for the main event as, three nights before he takes part in the Elimination Chamber Match for the World Heavyweight Championship, Rey Mysterio would go one-on-one with Mike Knox. In the end, it was Rey Mysterio hitting the 619 on Mike Knox en route to picking up the win and gaining momentum heading into the Elimination Chamber Match this Sunday! Can Rey overcome his five adversaries inside the Elimination Chamber to win the World Heavyweight Title?